The Kinetics of Crystallization of Calcium Fluoride
نویسنده
چکیده
A new method is described for studying reproducibly, the kinetics of crystallization of calcium fluoride under conditions of constant solution composition. The method can be used even at very low supersaturation. The rate is proportional to the square of the supersaturation, over the range of relative supersaturation, S = 0.20 1.66. The results point to a surface controlled crystallization. The rate is markedly influenced by the presence of phosphate.
منابع مشابه
Isothermal Melt Crystallization Kinetic Behavior of Poly (vinylidene fluoride)
Isothermal melt crystallization kinetics of PVDF was investigated by differential scanning calorimetry. Thin PVDF film has been fabricated by the solvent casting technique using dimethylformamide (DMF). Then, the samples were melted and subsequently crystallized in the range of the crystallization temperature (Tc) between 138 and 145 °C. The crystallization kinetics was derived from Avrami equa...
متن کاملKinetics Influence of Operation Conditions on Crystal Growth of Calcium Nitrate Tetrahydrate in a Circulating Fluidized Bed
In order to improve the traditional freezing crystallization process of calcium nitrate in nitric phosphate process, crystal growth experiments by adding Ca(NO3)2·4H2O seeds in supersaturated calcium nitrate solution in a Circulating Fluidized Bed (CFB) crystallizer were carried out on crystal growth kinetics. The results showed that the growth of C...
متن کاملInvestigation of Different Stages of Aluminum Fluoride Crystal Growth
Crystallization of Aluminum fluoride at atmospheric pressure has been considered. Structure, size and shape of crystals formed during the crystallization process have been investigated. By applying the direct analysis method for the existed aluminum in solution, the aluminum fluoride nucleation process has been detected as a concentration valley at the outset of crystallization process. The...
متن کاملCrystallization Kinetics and Characterization of Nanostructure Mica Glass-Ceramics with Optical Transparency
Transparent glasses in a system of Li2O-MgO-SiO2-Al2O3-Fchemical constituents were prepared by melt quenching method. In the fabrication of nanocrystal glass-ceramics, controlled nucleation and subsequent crystal growth were necessary to avoid loss of transparency. It was therefore important to understand thermal properties and crystallization kinetic...
متن کاملStudy of Non-Isothermal Crystallization Kinetics of Biodegradable Poly(ethylene adipate)/SiO2 Nanocomposites
Poly(ethylene adipte) and poly(ethylene adipate)/silica nanocomposite (PEAd/SiO2) containing 3 wt. % SiO2 were prepared by an in situ method. The examinations on the non-isothermal crystallization kinetic behavior have been conducted by means of differential scanning calorimeter (DSC). The Avrami, Ozawa, and combined Avrami and Ozawa equations were applied to describe the crystallization kinet...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2018